| 摘要: |
| 黑磷晶体的单原子层结构被定义为磷烯，它具有独特的褶皱形态和一些区别于其它二维晶体材料的特性，如可调控的直接带隙，高开关比，高载流子迁移率以及优异的光学饱和吸收特性等，使其在纳米电子和纳米光学领域具有潜在应用价值。此外，蓝磷烯被理论计算所预测，它是黑磷烯的一种同素异形体，具有许多类似黑磷烯的优异特性。本文主要介绍了当前两种构型磷烯的研究进展，包括黑/蓝磷烯各自的晶体结构、制备方法、物理特性和稳定性；最后对目前磷烯研究中存在的问题与挑战提出了一些见解和展望。 |
| 关键词: 磷烯 扫描隧道显微镜 二维材料 材料合成 |
| DOI： |
| 投稿时间：2021-10-19修订日期：2023-03-21 |
| 基金项目:国家自然科学基金(62104254);中国矿业大学重点学科经费(2022WLXK12) |
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| Synthesis and properties of phosphorene: recent progress and perspectives |
|
Zhang Xuan1, Zhang Wei2
|
| (1.School of Materials and Physics, China University of Mining and Technology;2.Universite Paris-Saclay, CNRS, Institut des Sciences Moleculaires d’Orsay) |
| Abstract: |
| Single layer black phosphorus was named as phosphorene, which has several properties that distinguish it from other 2D materials, including an intrinsic direct band gap, that can be tuned from 1.8 eV for a monolayer to 0.35 eV for bulk black phosphorus crystals, and high carrier mobility with high on/off ratio, high optical and UV absorption, and other attractive properties. These properties make phosphorene promising for applications in nanoelectronic and nano-optical devices. Inspired by the investigation of black phosphorene, a new attractive 2D phosphorus allotrope, blue phosphorene, has been predicted theoretically, which shares many excellent characteristics as black phosphorene with the buckled honeycomb lattice. Although phosphorene possesses attractive mechanical, electronic, optical and transport properties, the synthesis of phosphorene is still a major challenge. Herein, we summarize and highlight the recent progress in phosphorene research, touching upon topics preparation, isolation, characterization and properties, and also provide our insights and outlook on the future problems and challenges in phosphorene research. |
| Key words: Phosphorene Scanning tunneling microscopy Two-dimensional material Material synthesis |